Values CatLog read from this paper
Synthesis and enzymatic ketonization of the 5-(halo)-2-hydroxymuconates and 5-(halo)-2-hydroxy-2,4-pentadienoates
PMID 28684981doi:10.3762/bjoc.13.101Open in Browse
The paper itself is not on this site: read it at the publisher. This page lists only the values CatLog read from it.
CatLog read 19 records (57 values) from this paper: 4-oxalocrotonate tautomerase (Pp 4-OT), 4-oxalocrotonate tautomerase (Lc 4-OT) from Pseudomonas putida, Leptothrix cholodnii.
Read from the paper by an AI model and checked against the paper by a second, separate AI run; code converted the units. Values are in CatLog's units; each record opens in Browse with the line the paper prints and the checks.
| Enzyme | Organism | Substrate | kcat (s⁻¹) | Km (mM) | kcat/Km (mM⁻¹ s⁻¹) | Conditions | Open record |
|---|---|---|---|---|---|---|---|
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | (4Z)-5-bromo-2-hydroxy-2,4-pentadienoate | 13.2 | 0.29 | 46 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), (4Z)-5-bromo-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | (4Z)-5-bromo-2-hydroxymuconate | 420 | 0.06 | 7 × 10³ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), (4Z)-5-bromo-2-hydroxymuconate |
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | (4Z)-5-chloro-2-hydroxy-2,4-pentadienoate | 36 | 1.4 | 26 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), (4Z)-5-chloro-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | (4Z)-5-chloro-2-hydroxymuconate | 350 | 0.06 | 5.8 × 10³ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), (4Z)-5-chloro-2-hydroxymuconate |
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | (4Z)-5-fluoro-2-hydroxy-2,4-pentadienoate | 25 | 0.85 | 29 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), (4Z)-5-fluoro-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | (4Z)-5-fluoro-2-hydroxymuconate | 420 | 0.04 | 1.1 × 10⁴ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), (4Z)-5-fluoro-2-hydroxymuconate |
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | 2-hydroxy-2,4-pentadienoate | 2 | 0.42 | 4.8 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), 2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Lc 4-OT) | Leptothrix cholodnii | 2-hydroxymuconate | 2.4 × 10³ | 0.17 | 1.4 × 10⁴ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Lc 4-OT), 2-hydroxymuconate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-bromo-2-hydroxy-2,4-pentadienoateketonization of 5c to the alpha,beta-unsaturated ketone 9c | 1.7 | 0.32 | 5.3 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-bromo-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-bromo-2-hydroxy-2,4-pentadienoateketonization of 5c to the beta,gamma-unsaturated ketone 11c | 340 | 0.19 | 1.8 × 10³ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-bromo-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-bromo-2-hydroxymuconate | 210 | 0.032 | 6.6 × 10³ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-bromo-2-hydroxymuconate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-chloro-2-hydroxy-2,4-pentadienoateketonization of 5b to the alpha,beta-unsaturated ketone 9b | 0.5 | 1 | 0.5 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-chloro-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-chloro-2-hydroxy-2,4-pentadienoateketonization of 5b to the beta,gamma-unsaturated ketone 11b | 320 | 0.73 | 440 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-chloro-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-chloro-2-hydroxymuconate | 220 | 0.06 | 3.8 × 10³ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-chloro-2-hydroxymuconate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-fluoro-2-hydroxy-2,4-pentadienoate | 110 | 0.47 | 230 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-fluoro-2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | (4Z)-5-fluoro-2-hydroxymuconate | 630 | 0.034 | 1.9 × 10⁴ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), (4Z)-5-fluoro-2-hydroxymuconate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | 2-hydroxy-2,4-pentadienoateketonization of 5a to the alpha,beta-unsaturated ketone 9a | 2.9 | 1.6 | 1.8 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), 2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | 2-hydroxy-2,4-pentadienoateketonization of 5a to the beta,gamma-unsaturated ketone 11a | 150 | 0.35 | 430 | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), 2-hydroxy-2,4-pentadienoate |
| 4-oxalocrotonate tautomerase (Pp 4-OT) | Pseudomonas putida | 2-hydroxymuconate | 2.1 × 10³ | 0.1 | 2.1 × 10⁴ | pH 7.3, 24 °C | Open record: 4-oxalocrotonate tautomerase (Pp 4-OT), 2-hydroxymuconate |